首页/文章/ 详情

【新文速递】2025年7月14日复合材料SCI期刊最新文章

10小时前浏览2
 

 

今日更新:Composite Structures 4 篇,Composites Part A: Applied Science and Manufacturing 2 篇,Composites Part B: Engineering 3 篇,Composites Science and Technology 3 篇

Composite Structures

The effect of random microstructure morphology on the bending behavior of composite plate structures

Panagiotis Gavallas, George Stefanou, Eleftherios Tsivolas

doi:10.1016/j.compstruct.2025.119432

随机组织形态对复合板结构弯曲性能的影响

The uncertain behavior of composite materials can be attributed to their random microstructure. Uncertainty propagation from micro- to macroscale is usually simulated using homogenization methods where boundary conditions (BCs), such as tension and shear, are applied to determine effective mechanical properties. This work focuses on plate structures, whose properties cannot be accurately estimated by classical homogenization schemes. Instead, they are described using the ABD stiffness matrix defined by classical laminate theory (CLT) and effective stiffness is obtained by application of bending/torsional BCs. The ABD-matrix homogenization method is applied, along with the moving window technique, for the computation of random fields of bending properties based on CT images of a real short fiber composite. Random fields describing bending and axial/shear stiffness are extracted, and their statistics are compared. Appropriate random field models are selected based on the marginal distributions and autocorrelation functions of the microstructure-derived random fields, while cross-correlations between different stiffness components are also considered. Finally, these random field models are employed for the stochastic finite element analysis of composite plate structures, whose response variability is investigated in detail. Useful conclusions are derived regarding the effect of several parameters on the response variability, including model size, scale factor and cross-correlations.

复合材料的不确定性可归因于其随机的微观结构。不确定性从微观到宏观的传播通常使用均匀化方法来模拟,其中边界条件(bc),如张力和剪切,应用于确定有效的力学性能。本研究的重点是板结构,其性质不能准确估计的经典均质方案。相反,它们使用经典层压理论(CLT)定义的ABD刚度矩阵来描述,并通过应用弯曲/扭转bc来获得有效刚度。基于实际短纤维复合材料的CT图像,采用abd矩阵均匀化方法和移动窗口技术计算其弯曲性能随机场。提取了描述弯曲刚度和轴剪刚度的随机场,并对其统计量进行了比较。根据微结构衍生随机场的边际分布和自相关函数选择合适的随机场模型,同时考虑不同刚度分量之间的相互关系。最后,将这些随机场模型应用于复合材料板结构的随机有限元分析,详细研究了复合材料板结构的响应变异性。关于模型大小、比例因子和相互关系等参数对响应变异性的影响,得出了有用的结论。


Dynamic instability of elastically supported functionally graded porous arches reinforced with graphene platelets under a general dynamic load

Hao Tang, Airong Liu, Jian Deng, Jialin Wang, Jie Yang, Shimao Qin

doi:10.1016/j.compstruct.2025.119489

石墨烯片增强弹性支撑功能梯度多孔拱桥在一般动力荷载作用下的动力失稳

This paper investigates the in-plane dynamic instability behavior of elastically supported functionally graded porous (FGP) circular arches reinforced with graphene platelet-reinforced composite (FGP-GPLRC) under a general radial periodic dynamic load. By expressing the dynamic load in Fourier series, a comprehensive analysis of an FGP-GPLRC arch capable of dealing with various dynamic loading conditions is developed for the first time. The practical boundary conditions that are not fully rigidly restrained are modelled by elastic supports to enable a more accurate prediction of the dynamic stability of the arches. The governing equations of motion of the arch are derived and its dynamic instability regions are analytically determined. The present analysis is validated with excellent agreement with finite element results. A comprehensive parametric analysis is conducted to examine the effects of porosity distribution pattern, porosity coefficient, GPL mass fraction, elastic support, damping ratio, static load component, and dynamic load shape on the dynamic instability of the FGP-GPLRC arch. Our results indicate that the parametric resonance instability regions of an FGP-GPLRC arch under square-wave dynamic loads are significantly larger than those under sawtooth-wave and harmonic dynamic loads.

研究了石墨烯平板增强复合材料(FGP- gplrc)弹性支撑功能梯度多孔(FGP)圆拱在一般径向周期性动力载荷作用下的面内动力失稳行为。通过傅立叶级数表示动荷载,首次对能够处理各种动荷载条件的FGP-GPLRC拱桥进行了综合分析。对于没有完全刚性约束的实际边界条件,采用弹性支撑进行建模,以便更准确地预测拱的动力稳定性。推导了拱的运动控制方程,并解析确定了拱的动力失稳区域。本文的分析结果与有限元结果非常吻合。通过综合参数分析,考察了孔隙率分布规律、孔隙率系数、GPL质量分数、弹性支撑、阻尼比、静载分量、动载形状等因素对FGP-GPLRC拱动力失稳的影响。结果表明,FGP-GPLRC拱在方波动力载荷作用下的参数共振失稳区明显大于锯齿波和谐波动力载荷作用下的参数共振失稳区。


Emergence of anomalous hyperbolic heat conduction in homogenized media

Jean-François Ganghoffer, Xuan Nam Do, Sébastien Fumeron

doi:10.1016/j.compstruct.2025.119492

均质介质中反常双曲热传导的出现

Classical heat conduction, described by Fourier’s law, assumes an infinite thermal signal speed, which is physically unrealistic. Hyperbolic heat conduction models address this by introducing a finite wave speed, as seen in the Cattaneo–Vernotte (CV) equation, which modifies Fourier’s law with a time-delay term, leading to wave-like heat propagation. Extensions like the dual-phase-lag (DPL) and nonlocal theories enhance heat transport modeling in micro- and nanoscale materials, biological tissues, and laser-irradiated surfaces. Despite significant developments since the 1950 s, most hyperbolic heat conduction models remain phenomenological, lacking predictive capability. We develop in this contribution homogenization-based approaches for upscaling the classical parabolic heat model that prevails in acoustically thick media at the microscale of the individual components of periodic heterogeneous materials towards generalized heat theories incorporating additional higher-order variables and parameters, prone to weak or strong nonlocality. Based on a Hill-Mandel energy equivalence principle and localization relations of the micro-fields to their macroscopic counterpart in the postulated effective heat theory, the effective heat properties including relaxation times and internal lengths are formally evaluated in terms of volume averages over an identified unit cell of the microscopic heat properties and localization operators. Those localization operators solve unit cell boundary-value problems with periodicity conditions. In the second part of the paper, we rely on the Floquet-Bloch transform to formulate nonlocal emergent heat theories, in which the macroscopic heat flux is written as a convolution integral of a kernel with the temperature. Applications to 1D periodic composites illustrate the established methodology to compute the effective heat properties of the emergent hyperbolic heat conduction theory.

傅立叶定律描述的经典热传导假设热信号速度无限,这在物理上是不现实的。双曲热传导模型通过引入有限的波速来解决这个问题,正如在Cattaneo-Vernotte (CV)方程中所见,它用一个时滞项修改了傅里叶定律,导致了波状热传播。双相滞后(DPL)和非局部理论等扩展增强了微纳米材料、生物组织和激光照射表面的热传输建模。尽管自1950年 以来取得了重大进展,但大多数双曲热传导模型仍然是现象学的,缺乏预测能力。在这一贡献中,我们发展了基于均质化的方法,将经典抛物线热模型升级,该模型在周期性非均质材料的单个组分的微观尺度上普遍存在于声学厚介质中,向包含附加高阶变量和参数的广义热理论发展,容易出现弱或强非定域性。基于Hill-Mandel能量等效原理和假设有效热理论中微观场与宏观场的局域化关系,根据微观热性质和局域化算子的确定单元胞的体积平均值,正式评估了包括松弛时间和内部长度在内的有效热性质。这些定位算子解决具有周期性条件的单元胞边值问题。在论文的第二部分,我们依靠Floquet-Bloch变换来建立非局部涌现热理论,其中宏观热流被写成核与温度的卷积积分。在一维周期复合材料中的应用说明了新兴双曲热传导理论计算有效热性能的既定方法。


Composites Part A: Applied Science and Manufacturing

Flame-retardant composites from recycled PET fibers and soybean oil-based resins: A sustainable solution for honeycomb panel skins

Yizhen Chen, Liyuan Zhang, Renhui Qiu, Tingting Chen, Mingen Fei, Wendi Liu

doi:10.1016/j.compositesa.2025.109164

由回收PET纤维和大豆油基树脂制成的阻燃复合材料:蜂窝板皮肤的可持续解决方案

A sustainable and flame-retardant composite facing layers was developed using recycled polyethylene terephthalate (rPET) fiber-mats and renewable soybean oil-based resins. The rPET fiber-mats were surface-treated with a finishing agent composed of paraformaldehyde and dicyandiamide. This finishing agent can interact with the fiber surface both physically and chemically, aiming to enhance composite interfacial adhesion. A flame-retardant soybean oil-based resin, from epoxidized soybean oil, tannic acid, and 2-hydroxyethyl methacrylate phosphate, was used as the matrix. The composites exhibited a limited oxygen index of 28.68%, with reduced heat release and flue gas emission during combustion. The treatment of rPET fibers contributed to improvements in thermal and mechanical properties of the composites. When used as outer layers, this composite also enhanced both flame retardancy and mechanical performance of the paper honeycomb panels. This study introduces an innovative approach to replacing traditional nonrenewable and flammable facing layers in honeycomb panels with recycled and renewable materials.

采用再生聚对苯二甲酸乙二醇酯(rPET)纤维垫和可再生大豆油基树脂,研制了一种可持续阻燃的复合饰面层。用多聚甲醛和双氰胺组成的整理剂对rPET纤维垫进行表面处理。该整理剂可与纤维表面发生物理和化学作用,旨在增强复合材料界面的附着力。以环氧大豆油、单宁酸和磷酸甲基丙烯酸2-羟乙酯为基体制备阻燃大豆油基树脂。复合材料的限氧指数为28.68%,燃烧过程中的热释放和烟气排放减少。rPET纤维的处理有助于提高复合材料的热性能和力学性能。当用作外层时,该复合材料也增强了纸蜂窝板的阻燃性和机械性能。本研究介绍了一种创新的方法,用回收和可再生材料取代蜂窝板中传统的不可再生和易燃的饰面层。


Interaction modulation of diphosphate piperazine and melamine phosphate for enhanced water resistance and flame retardancy in polypropylene

Weiwen Gu, Rui Wang, Huaibo Qian, Jingyu Zhang, Jiang Jing, Hongfei Li, Xiaoyu Gu, Sheng Zhang

doi:10.1016/j.compositesa.2025.109177

 

二磷酸哌嗪和三聚氰胺磷酸盐的相互作用调制增强聚丙烯的耐水性和阻燃性

This study reports our recent effort to address the key challenges of hydrophilicity and inefficiency for conventional intumescent flame retardants (IFRs) through the regulation of interaction modes. Three interaction modes are designed through physical blending (DPAPI/MP, astatic binding), core–shell structure (DPAPI@MP, weak chemical interaction), and covalent bonding (DPAPI-MP, strong chemical interaction). The effect of different interaction modes between piperazine diphosphate (DPAPI) and melamine phosphate (MP) on flame retardancy is analyzed. The introduction of only 20 wt% DPAPI-MP into the PP matrix significantly enhances its flame retardant properties, raising the limiting oxygen index (LOI) increase from 17.2 % to 27.8 % and achieving a UL-94 V-0 rating. The peak heat release rate (PHRR) and total smoke release (TSR) decreased by 79 % and 54 %, respectively. The residual char increases to 29.4 % from 0. The flame retardant mechanism involves a topological rearrangement of the triazine ring, which releases non-combustible gases, while acidic compounds facilitate the development of a three-dimensional P-O-C cross-linked structure. For water-resistant performance the PP/DPAPI-MP/RDP cretained the UL-94 V-0 rating even after 168 h of hydrothermal aging at 70 °C. The precipitation rate is reduced to 1.18 wt%, and the tensile strength decreases by only 1.5 %. The PP/DPAPI-MP/RDP exhibit an excellent balance between flame retardancy and water resistance. This study proposes a novel design concept for regulating the interaction modes of flame retardants, offering new insights into the development of water resistant and flame retardant PP.

本研究报告了我们最近的努力,通过调节相互作用模式来解决传统膨胀型阻燃剂(IFRs)的亲水性和低效率的关键挑战。通过物理共混(DPAPI/MP,静态结合)、核壳结构(DPAPI@MP,弱化学相互作用)和共价键(DPAPI-MP,强化学相互作用)设计了三种相互作用模式。分析了二磷酸哌嗪(DPAPI)与磷酸三聚氰胺(MP)不同相互作用方式对阻燃性能的影响。仅在PP基体中加入20 wt%的DPAPI-MP就能显著提高其阻燃性能,将极限氧指数(LOI)从17.2 %提高到27.8 %,达到UL-94 V-0等级。峰值热释放率(PHRR)和总烟释放率(TSR)分别下降了79 %和54 %。剩余炭从0增加到29.4 %。阻燃机理涉及三嗪环的拓扑重排,释放不可燃气体,而酸性化合物促进三维P-O-C交联结构的发展。在70 °C水热老化168 h后,PP/DPAPI-MP/RDP的防水性能仍达到UL-94 V-0等级。析出率降低到1.18 wt%,抗拉强度仅降低1.5 %。PP/DPAPI-MP/RDP在阻燃性和耐水性之间表现出良好的平衡。本研究提出了一种调节阻燃剂相互作用模式的新设计理念,为耐水阻燃PP的发展提供了新的见解。


Composites Part B: Engineering

Multi-Scale Stochastic Study of Glass Fiber Sizing Effects in Automotive Structural Sheet Molding Compounds

William J. Henken, Stephen Young, Vivek Chawla, Cecile A. Grubb, Rebecca E. Bergee, Mohamed M. Selim, Jonathan McKay, Hendrik Mainka, Marton Kardos, Dayakar Penumadu

doi:10.1016/j.compositesb.2025.112795

玻璃纤维在汽车结构板材成型材料中施胶效应的多尺度随机研究

Three commercially available sizings A, B, and C were studied in this work based on their target use towards class-A, semi-structural, and general-purpose SMC formulations. Each chemical sizing treatment A, B, and C was compounded on a pilot-scale SMC line with target 55 wt.% fiber content using the same paste formulation suitable for high fiber content. Compression molding and sample preparation was conducted systematically and consistently to minimize variance when comparing test results. Notable differences in wetting and sheet density of the compounded charges were observed. After compression molding one chemical sizing exhibited blister defects on the panel surfaces of approximately 1/3rd of the molded panels, indicating the entrapment of air during flow which was not observed in the other compounds. ANOVA revealed significant differences (17 % – 20 %) in IFSS at the fiber-matrix interface resulting from chemical sizing. Despite these observed differences, ANOVA revealed no significant differences in quasi-static tension, shear, flexure, or compression properties of molded panels containing the different glass fiber sizings. This work concludes that chemical sizing significantly affects SMC compounding, molding, and microscale IFSS. Provided the composites can consolidate without the formation of blister defects, the overall structural performance is not observed to change statistically when considering inherent sources of variability stemming from localized effects of fiber volume and fiber orientation at the mesoscale. Outcomes of this work allow for greater confidence in producing semi-structural SMC components using generalized chemical sizing packages as long as consolidation of SMC parts is achieved through compounding and molding.

本文研究了三种市售浆料A、B和C在A类、半结构和通用SMC配方中的目标用途。每种化学施胶处理A、B和C在中试SMC生产线上复合,目标纤维含量为55wt .%,使用适用于高纤维含量的相同浆料配方。压缩成型和样品制备进行系统和一致,以尽量减少差异时比较测试结果。观察到复合电荷的润湿性和片密度的显著差异。压缩成型后,一种化学浆料在大约1/3的模压板表面显示出水泡缺陷,这表明在流动过程中空气被困住了,这在其他化合物中没有观察到。方差分析显示,化学施胶导致纤维-基质界面的IFSS差异显著(17% - 20%)。尽管存在这些观察到的差异,方差分析显示含有不同玻璃纤维浆料的模塑板在准静态张力、剪切、弯曲或压缩性能方面没有显著差异。这项工作得出结论,化学施胶显著影响SMC复合,成型和微尺度IFSS。如果复合材料可以在不形成泡状缺陷的情况下进行固结,那么考虑到纤维体积和纤维取向在中尺度上的局部影响所产生的固有变异源时,总体结构性能在统计上不会发生变化。这项工作的结果允许更大的信心在生产半结构SMC组件使用通用的化学尺寸封装,只要SMC部件的巩固是通过复合和成型实现。


Advanced hollow ball-cactus-like soft-magnetic LDH@MXeneHT nanohybrid materials towards highly efficient electromagnetic protection

Yaqiang Duan, Weijun Yang, Yong Zhang, Yuchen Gu, Pengwu Xu, Deyu Niu, Yunpeng Huang, Shiqiang Song, Debora Puglia, Piming Ma

doi:10.1016/j.compositesb.2025.112807

 

先进的空心球形仙人掌状软磁LDH@MXeneHT纳米杂化材料,实现高效电磁防护

In order to improve the comprehensive electromagnetic protection and meet the aerospace demands, designing the microstructure of functional nanomaterials is an effective strategy. Inspired by the special structure of the ball-cactus, in this work, soft-magnetic nanohybrid materials are realized for highly efficient electromagnetic protection. Layered double FeNi3 hydroxide (LDH) is in-situ nucleated and grown on the surface of MXene via synchronous electrostatic self-assembling, leading to an intermediate product - LDH@MXene - with a hydrangea microstructure (diameter ∼5 μm). LDH@MXene is subsequently annealed at 500 °C to obtain a hollow ball-cactus-like LDH@MXeneHT500 nanohybrid, by transforming the lamellar “petals” of the hydrangea structure into burr-like structures. LDH@MXeneHT500 has soft-magnetic characteristics, facilitating the transport of induced charges and the consumption of electromagnetic energy. Therefore, LDH@MXeneHT500 nanohybrid exhibits excellent comprehensive electromagnetic protection capabilities, such as high reflection loss (RLmin = -76.1 dB) in a wide absorption bandwidth (EAB = 6.12 GHz), and high electromagnetic interference shielding efficiency (EMI SE = 47.2 dB in X band). To broaden its application, poly(dimethylsiloxane) (PDMS)/LDH@MXeneHT500 nanocomposites are further prepared that exhibit improved mechanical strength (9.48 MPa) and highly efficient electromagnetic protection performances (RLmin = -65.11 dB and EAB = 7.64 GHz, EMI SE > 50 dB in 3-18 GHz). Therefore, both the LDH@MXeneHT500 nanohybrid materials and PDMS/LDH@MXeneHT500 nanocomposites show great potential in electromagnetic protection applications, such as in the area of aerospace and satellite communication.

为了提高电磁综合防护性能,满足航空航天需求,对功能纳米材料进行微结构设计是一种有效的策略。受球形仙人掌特殊结构的启发,本研究实现了软磁纳米杂化材料的高效电磁防护。层状双氢氧化氢FeNi3 (LDH)通过同步静电自组装在MXene表面原位成核并生长,得到了具有绣球结构(直径~ 5 μm)的中间产物LDH@MXene。LDH@MXene随后在500°C下退火,通过将绣球结构的片层“花瓣”转变为毛刺状结构,获得空心球状仙人掌状LDH@MXeneHT500纳米杂交种。LDH@MXeneHT500具有软磁特性,有利于感应电荷的输运和电磁能量的消耗。因此,LDH@MXeneHT500纳米混合材料在较宽的吸收带宽(EAB = 6.12 GHz)下具有较高的反射损耗(RLmin = -76.1 dB),在X波段具有较高的电磁干扰屏蔽效率(EMI SE = 47.2 dB),具有优异的综合电磁保护能力。为了扩大其应用范围,进一步制备了聚二甲基硅氧烷(PDMS)/LDH@MXeneHT500纳米复合材料,该复合材料具有更高的机械强度(9.48 MPa)和高效的电磁保护性能(RLmin = -65.11 dB, EAB = 7.64 GHz, EMI SE >在3-18 GHz范围内为50 dB)。因此,LDH@MXeneHT500纳米杂化材料和PDMS/LDH@MXeneHT500纳米复合材料在电磁保护领域,如航空航天和卫星通信领域显示出巨大的应用潜力。


Synergistic Effects of Nanosecond Pulse Laser and Atmospheric Plasma Treatments on Enhancing the Interface Fatigue Performance of PA11-CFRP in Type IV Hydrogen Storage Tanks

Lele Cheng, Liangliang Qi, Qinan Li, Zhonghao Mei, Keqing Wang, Ruize Gao, Jie Xiao, Muhuo Yu, Zeyu Sun

doi:10.1016/j.compositesb.2025.112809

纳秒脉冲激光和大气等离子体处理对提高IV型储氢罐PA11-CFRP界面疲劳性能的协同效应

The development of Type IV high-pressure hydrogen storage tanks faces persistent technical challenges, particularly in preventing the structural degradation of polymer liners. During operational cycles, repeated hydrogen filling and degassing processes impose severe interfacial fatigue on the bond between the thermoplastic liner and the carbon fiber-reinforced polymer (CFRP) composite overwrap. Improving adhesion integrity at the PA11-CFRP interface is critical for mitigating the risks associated with liner rupture. To address this challenge, a synergistic surface modification strategy for PA11 liners combining laser texturing with plasma activation was implemented. The interfacial fatigue performance was quantitatively evaluated via flatwise tensile (FWT) testing, incorporating S-N curve analysis and progressive stiffness degradation metrics. Notably, the laser-plasma co-treatment significantly improved the interfacial fatigue resistance of PA11-CFRP compared to untreated controls or individually modified surfaces, such as laser-only or plasma-only treatments. The underlying mechanism governing interface bonding durability was explored through multiscale characterization, including microstructural evolution at the PA11-CFRP interface, surface topography and roughness parameters, thermodynamic surface energy components, and chemical functionalities of activated interfacial groups. These findings establish a theoretical foundation for analyzing interface fatigue failures in large-scale applications of Type IV hydrogen storage tanks.

IV型高压储氢罐的开发面临着持续的技术挑战,特别是在防止聚合物衬垫结构降解方面。在操作周期中,反复的充氢和脱气过程会对热塑性衬垫和碳纤维增强聚合物(CFRP)复合材料包覆层之间的粘合产生严重的界面疲劳。提高PA11-CFRP界面的粘合完整性对于降低衬垫破裂的风险至关重要。为了解决这一问题,研究人员采用了一种结合激光变形和等离子体活化的协同表面改性策略。通过平面拉伸(FWT)测试,结合S-N曲线分析和渐进式刚度退化指标,定量评估界面疲劳性能。值得注意的是,与未经处理的对照或单独修饰的表面(如仅激光或仅等离子体处理)相比,激光等离子体共处理显著提高了PA11-CFRP的界面抗疲劳性。通过多尺度表征,包括PA11-CFRP界面的微观结构演变、表面形貌和粗糙度参数、热力学表面能组分和活化界面基团的化学官能团,探索了控制界面结合耐久性的潜在机制。研究结果为IV型储氢罐大规模应用界面疲劳失效分析奠定了理论基础。


Composites Science and Technology

Developing Wearable Photothermal and Antibacterial Fabrics: In-Situ Polymerization of MoS2-Hybridized PET Fibers

Hongchuang Li, Zhou Sha, Yuheng Song, Jiahui Fan, Jiaxian Wei, Yuchi Fan, Xiang Fei, Meifang Zhu

doi:10.1016/j.compscitech.2025.111291

 

开发可穿戴光热抗菌织物:mos2杂交PET纤维的原位聚合

The burgeoning field of smart textiles, particularly those with photothermal conversion capabilities, is driven by the escalating need for energy-efficient and versatile thermoregulation solutions across healthcare, energy, and personal protection applications. Despite the promising potential of two-dimensional transition metal dichalcogenides (e.g. MoS2), their practical implementation has been hindered by challenges such as aggregation and the lack of a one-step continuous spinning process for the fabrication of high-performance photothermal fibers. This study addresses these gaps by employing in-situ polymerization to integrate MoS2 with polyethylene terephthalate (PET) polymer, yielding the PET/MoS2 fibers and fabrics that exhibits excellent photothermal antibacterial properties. The uniform distribution of MoS2 within the PET matrix not only improved the fiber’s mechanical integrity but also significantly enhanced its photothermal performance and antibacterial activity under photothermal conditions. The tensile strength of the fabric was observed to increase with the incorporation of MoS2 up to an optimal loading amount. The photothermal performance was found to be exceptional under various light sources, with a direct correlation to the MoS2 content. The antibacterial efficacy was notably robust, achieving a 95% reduction in both Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus) under near-infrared irradiation. This study offers a scalable and efficient solution for advanced wearable thermal management, poised to redefine the future of personal comfort and healthcare technology.

智能纺织品领域的蓬勃发展,特别是那些具有光热转换功能的智能纺织品,是由医疗保健、能源和个人防护应用领域对节能和多功能温度调节解决方案不断增长的需求推动的。尽管二维过渡金属二硫化物(如MoS2)具有很大的潜力,但它们的实际实施受到诸如聚集和缺乏用于制造高性能光热纤维的一步连续纺丝工艺等挑战的阻碍。本研究通过原位聚合将MoS2与聚对苯二甲酸乙二醇酯(PET)聚合物结合,得到了具有优异光热抗菌性能的PET/MoS2纤维和织物,从而解决了这些空白。MoS2在PET基体内的均匀分布不仅提高了纤维的机械完整性,而且显著提高了其光热性能和光热条件下的抗菌活性。织物的抗拉强度随着二硫化钼的加入而增加,直至最佳加载量。光热性能在不同的光源下表现优异,与MoS2含量直接相关。抗菌效果显著,在近红外照射下,大肠杆菌(E. coli)和金黄色葡萄球菌(S. aureus)的抗菌效果均降低95%。这项研究为先进的可穿戴热管理提供了一个可扩展和高效的解决方案,准备重新定义个人舒适和医疗保健技术的未来。


Transfer learning-guided generative laminate design framework with limited data availability

Siyuan Chen, Zhixing Li, Jinzhao Huang, Tiantian Yang, Yunpeng Gao, Jia Hu, Guang Yang, Licheng Guo

doi:10.1016/j.compscitech.2025.111292

 

数据有限的迁移学习导向生成层压板设计框架

Fiber-reinforced composites offer significant tailoring potential, but extensive design parameters and the need to explore new design spaces pose substantial challenges in laminate designs. This paper presents a Transfer learning-guided Generative Laminate Design Framework (TGLDF) to efficiently extend design spaces with limited data availability. A generator in the TGLDF rapidly produces design parameters bounded within design ranges through a data scaling method, along with a neural network-based discriminator fine-tuned with small datasets to predict mechanical properties within new design spaces. Customized generation losses are incorporated to enable the generations to achieve design objectives, such as desired strength and torsional stiffness in this paper. Two examples were used to validate the TGLDF under different new design spaces. These examples include notched laminates under uniaxial tension and composite tubes subjected to coupled internal pressure and axial compression, involving new materials, ply numbers, and loading conditions. The results show that only small datasets are needed to perform inverse design in these new design spaces. A comparative analysis with finite element simulations and Genetic Algorithms (GAs) demonstrates the effectiveness and superiority of the TGLDF, which outperforms GAs by integrating random noise to learn the distribution of optimal solutions. In addition, the concatenating of one-hot encodings and continuous parameters enables the TGLDF to extend to other design scenarios easily.

纤维增强复合材料提供了巨大的定制潜力,但广泛的设计参数和探索新设计空间的需求对层压板设计构成了重大挑战。本文提出了一种迁移学习引导的生成层叠设计框架(TGLDF),以有效地扩展数据可用性有限的设计空间。TGLDF中的生成器通过数据缩放方法快速生成设计范围内的设计参数,以及基于神经网络的鉴别器,通过小数据集进行微调,以预测新设计空间内的机械性能。在本文中,为了使代能够达到设计目标,例如期望的强度和扭转刚度,引入了定制的代损失。通过两个实例验证了TGLDF在不同新设计空间下的有效性。这些例子包括单轴拉伸下的缺口层压板和耦合内压和轴向压缩下的复合管,涉及新材料、层数和加载条件。结果表明,在这些新的设计空间中,只需要少量的数据集就可以进行逆向设计。通过与有限元仿真和遗传算法(GAs)的对比分析,证明了TGLDF算法的有效性和优越性,该算法通过集成随机噪声来学习最优解的分布,优于遗传算法。此外,单热编码和连续参数的连接使TGLDF能够轻松扩展到其他设计场景。


Investigating the Interchangeability of Low-Velocity Impact and Quasi-Static Indentation Tests: Effects on the Residual Strength of Hybrid Aluminum/CFRP Laminates

Musthafa Akbar, Satoshi Kobayashi

doi:10.1016/j.compscitech.2025.111293

 

低速冲击和准静态压痕试验的互换性研究:对铝/碳纤维复合材料层合板残余强度的影响

This study uses numerical methods, validated through laboratory experiments, to compare the mechanical behavior of hybrid aluminum/CFRP laminates under low-velocity impact (LVI) and quasi-static indentation (QSI) loading conditions. The study demonstrates that although both loading types show comparable force-displacement responses within a limited range, the divergence increases at higher LVI energy levels. Oscillations in the LVI force-displacement curve become more pronounced due to inertia and damage formation. In terms of damage, intralaminar failure in CFRP layers occurs under both loading conditions, but delamination is more pronounced under LVI loading. The study also finds that QSI produces more visible contact traces on the specimen surface compared to LVI, with smaller indenters resulting in clearer damage patterns. Simulations of tensile strength after impact reveal that LVI leads to lower residual tensile strength compared to QSI. Based on these findings, we conclude that QSI can be used as a substitute for LVI testing under certain conditions, particularly for low-impact energies (5-15 J), where delamination does not occur. However, for higher impact energies (20-30 J), significant differences in damage mechanisms indicate that the two methods should not be considered interchangeable for all applications. Further research is needed to establish clear criteria for using quasi-static tests as substitutes for low-velocity impact tests, especially for specific material configurations and conditions.

本研究采用数值方法,通过室内实验验证,比较了低速冲击(LVI)和准静态压痕(QSI)加载条件下铝/CFRP复合材料的力学行为。研究表明,尽管两种加载类型在有限范围内表现出相似的力-位移响应,但在LVI能量水平较高时,差异增大。由于惯性和损伤的形成,LVI力-位移曲线的振荡变得更加明显。损伤方面,两种加载条件下CFRP层均发生层内破坏,但在LVI加载下分层更为明显。研究还发现,与LVI相比,QSI在试样表面产生更多可见的接触痕迹,更小的压痕导致更清晰的损伤模式。对冲击后拉伸强度的模拟表明,与QSI相比,LVI导致的残余拉伸强度更低。基于这些发现,我们得出结论,在某些条件下,QSI可以作为LVI测试的替代品,特别是在低冲击能量(5-15 J)的情况下,不会发生分层。然而,对于更高的冲击能量(20-30 J),损伤机制的显著差异表明,这两种方法不应被认为是可互换的所有应用。需要进一步研究,以确定使用准静态试验代替低速冲击试验的明确标准,特别是针对特定的材料结构和条件。


来源:复合材料力学仿真Composites FEM
ACTMechanicalSystemFluxInspire疲劳复合材料燃烧化学通用航空航天汽车通信声学理论材料多尺度
著作权归作者所有,欢迎分享,未经许可,不得转载
首次发布时间:2025-07-23
最近编辑:10小时前
Tansu
签名征集中
获赞 11粉丝 4文章 908课程 0
点赞
收藏
作者推荐

【新文速递】2025年6月18日复合材料SCI期刊最新文章

今日更新:Composite Structures 1 篇,Composites Part A: Applied Science and Manufacturing 6 篇,Composites Part B: Engineering 6 篇Composite StructuresA flutter reliability optimization approach for aerospace composite structures based on adaptive ensemble modelHuagang Lin, Hui Feng, Haizheng Song, Zhufeng Yue, Zhichun Yangdoi:10.1016/j.compstruct.2025.119402基于自适应系综模型的航空复合材料颤振可靠性优化方法Uncertain factors generally exist in aeroelasticity systems, and ignoring their impacts can potentially result in unexpected flutter failures. Additionally, the computational cost of integrating flutter reliability with optimization is significant, as it requires a large number of expensive model evaluations to estimate the failure probability for each distribution parameter. In this paper, a new decoupled flutter reliability optimization method based on adaptive ensemble model is proposed, which fully leverages the advantages of each surrogate model and no additional original model evaluation is required. Firstly, flutter modelling is presented for supersonic composite plate embedded in Shape Memory Alloys (SMA). Secondly, an ensemble model is proposed to estimate the Failure Probability Function (FPF) with enhancing accuracy and efficiency by assigning specific weights to each individual model. The flutter reliability optimization is then decoupled using the FPF. Finally, a highly nonlinear function is employed to demonstrate the validity and computational efficiency of the proposed method compared to DLMCRO, DROAK and DROAPCK method. Two numerical applications including composite plate with SMA and wing model with engine considering the reliability and deterministic optimization are discussed.气动弹性系统中普遍存在不确定因素,忽视不确定因素的影响可能会导致系统颤振失效。此外,将颤振可靠性与优化相结合的计算成本很高,因为它需要大量昂贵的模型评估来估计每个分布参数的失效概率。本文提出了一种基于自适应集成模型的颤振可靠性解耦优化方法,该方法充分利用了各个代理模型的优点,无需对原始模型进行评估。首先建立了嵌入形状记忆合金(SMA)的超声速复合材料板的颤振模型。其次,提出了一种集成模型,通过对单个模型赋予特定的权重,提高了失效概率函数估计的准确性和效率。然后使用FPF解耦颤振可靠性优化。最后,通过一个高度非线性函数与DLMCRO、DROAK和DROAPCK方法进行比较,验证了该方法的有效性和计算效率。讨论了考虑可靠性和确定性优化的复合材料板和带发动机的机翼模型两种数值应用。Composites Part A: Applied Science and ManufacturingMechanical characterisation of GF-PET composite manufactured via in-situ Solid-State Polymerisation routeO. Vetterli, R. Krüger, S. Hentzen, G.A. Pappas, P. Ermannidoi:10.1016/j.compositesa.2025.109073 原位固态聚合制备GF-PET复合材料的力学特性The work reported in this short communication focusses on the impact of solid-state polymerisation (SSP) of glass fibre-poly(ethylene terephthalate) (GF-PET) composites, on polymer’s, interface’s, and eventually composite’s performance characterized through transverse tensile testing. Comparison with a state-of-the-art film stacking process revealed that similar, but also improved mechanical performance can be achieved by composites produced via the in-situ (i.e., at composite lamina level) SSP method. When the polymer is reacted at long intervals to achieve high molecular weights in-situ, a robust matrix-fibre interface is apparently formed, yielding fully cohesive failure of the composite (on fully desized fibres), while the improved polymer’s ductility enhances further the transverse performance. Composite’s ultimate transverse tensile strength saturation was found at a PET intrinsic viscosity of 0.82 dL/g, with values of ∼ 60 MPa, and ultimate strain of ∼ 0 . 82 % , with the latter to show a slight increase when the intrinsic viscosity reached 0.95 dL/g, through even longer SSP times. Thus, the prevalent challenges in thermoplastic reinforced composites, namely high processing viscosity and a weak matrix-fibre interface, are effectively addressed by the developed in-situ SSP route.在这篇简短的文章中报道的工作重点是玻璃纤维-聚对苯二甲酸乙二醇酯(GF-PET)复合材料的固态聚合(SSP)对聚合物、界面以及最终复合材料性能的影响,这些性能通过横向拉伸测试来表征。与最先进的薄膜堆积工艺相比,通过原位(即复合材料层)SSP方法生产的复合材料可以获得类似的力学性能,但力学性能也有所提高。当聚合物经过长时间的原位反应以获得高分子量时,显然会形成坚固的基质-纤维界面,导致复合材料(在完全粒径化的纤维上)完全内聚失效,而改进的聚合物的延展性进一步增强了横向性能。在PET特性粘度为0.82 dL/g时,复合材料的极限横向抗拉强度饱和值为~ 60 MPa,极限应变为~ 0。82%,当特性粘度达到0.95 dL/g时,后者通过更长的SSP时间略有增加。因此,热塑性增强复合材料的普遍挑战,即高加工粘度和弱基质-纤维界面,通过开发的原位SSP路线有效地解决了。A synergetic approach to enhancing mechanical properties of trace TiB2 particles reinforced AZ91D composites through α-Mg grain refinement and β-Mg17Al12 manipulationZelong Du, Xueqiang Yang, Qing Wang, Hangze Wu, Kai Zhao, Lei Liu, Zongning Chen, Zhirou Zhang, Enyu Guo, Huijun Kang, Tongmin Wangdoi:10.1016/j.compositesa.2025.109114α-Mg晶粒细化和β-Mg17Al12处理协同提高微量TiB2颗粒增强AZ91D复合材料力学性能Cast AZ91D magnesium alloys are plagued by coarse α-Mg grains and continuous β-Mg17Al12 phases that compromise mechanical performance. This work proposes a TiB2 particle-reinforced AZ91D composite strategy that simultaneously addresses both challenges through interfacial engineering. Introducing trace 0.3 wt.% TiB2 particles into the AZ91D alloy enables refinement via coupled heterogeneous nucleation and growth restriction effects. The identified crystallographic orientation relationship ([112¯0]Mg//[112¯0]TiB2, and (011¯0)Mg//(0001)TiB2) confirms effective α-Mg nucleation on TiB2 interfaces, reducing grain size by 64.4% to 68.2 μm. Concurrently, the β-Mg17Al12 phase morphology transitions from a typical continuous network to a dispersed small block or spherical structure through grain boundary pinning effects enabled by the refined microstructure. The yield strength, ultimate tensile strength, and elongation of AZ91D with 0.3 wt.% TiB2 particles are 129.2 MPa, 247.0 MPa, and 8.5%, respectively, which are increased by 9.1%, 26.3%, and 63.4% compared to the particle-free AZ91D alloy. This interfacial design strategy not only deciphers the particle–matrix interaction mechanisms in Mg-based composites but also provides insight into the development of refiners for cast Mg alloys.AZ91D 镁合金存在粗大的α-Mg 晶粒和连续的β-Mg17Al12 相,这严重影响了其机械性能。本研究提出了一种通过界面工程引入 0.3 重量%的 TiB2 颗粒增强 AZ91D 复合材料的策略,以同时解决这两个问题。微量的 0.3 重量% TiB2 颗粒的引入通过异质形核和生长限制的耦合作用实现了细化。所确定的晶体学取向关系([112¯0]Mg//[112¯0]TiB2,以及 (011¯0)Mg//(0001)TiB2)证实了α-Mg 在 TiB2 界面的有效形核,使晶粒尺寸减小了 64.4%至 68.2 微米。同时,由于细化后的微观结构产生的晶界钉扎效应,β-Mg17Al12 相的形态从典型的连续网络转变为分散的小块状或球状结构。添加 0.3 重量% TiB2 颗粒的 AZ91D 合金的屈服强度、抗拉强度和伸长率分别为 129.2 MPa、247.0 MPa 和 8.5%,分别比不含颗粒的 AZ91D 合金提高了 9.1%、26.3%和 63.4%。这种界面设计策略不仅揭示了镁基复合材料中颗粒与基体的相互作用机制,还为铸造镁合金细化剂的开发提供了思路。In-situ tailored repair of thermoplastic composites by overprinting of continuous carbon fibre reinforced polymer filamentsYahui Lyu, Aonan Li, Jiang Wu, Haoqi Zhang, Dongmin Yangdoi:10.1016/j.compositesa.2025.109117连续碳纤维增强聚合物长丝叠印热塑性复合材料的原位定制修复This study proposes an efficient and convenient in-situ repair approach for damaged thermoplastic composites by 3D overprinting. Continuous carbon fibre reinforced polyphenylene sulphide (CCF/PPS) filament was employed to overprint repair patches onto conventionally manufactured woven polyamide 6 (PA6) laminates. The process window was optimised through thermal analysis of the target polymers, with a temperature range spanning from the melting point of PA6 (216.8°C) to the crystallisation point of PPS (227.6°C). A nominated interface temperature of 220 °C was evidenced as the most effective, raising the tensile strength of repaired specimens to 205.9 MPa, an improvement of 35 % compared to open-hole laminates and a recovery of nearly 50 % of the strength lost relative to undamaged specimens. Additionally, bio-inspired spider web printing paths were tailored for static indention loading, restoring 94 % of the original laminate strength while reducing material usage by 67 % compared to conventional unidirectional patches. This novel overprinting approach offers a highly efficient and flexible solution for repairing damaged thermoplastic structures.本研究提出了一种高效、便捷的热塑性复合材料三维叠印原位修复方法。采用连续碳纤维增强聚苯硫醚(CCF/PPS)长丝将修复贴片套印到传统制造的编织聚酰胺6 (PA6)层压板上。通过对目标聚合物的热分析,优化了工艺窗口,温度范围从PA6的熔点(216.8°C)到PPS的结晶点(227.6°C)。220 °C的指定界面温度被证明是最有效的,将修复后的试样的抗拉强度提高到205.9 MPa,与裸眼层合板相比提高了35% %,相对于未损伤的试样,恢复了近50% %的强度损失。此外,仿生蜘蛛网打印路径是为静态压痕负载量身定制的,与传统的单向贴片相比,恢复了94 %的原始层压板强度,同时减少了67 %的材料使用量。这种新颖的叠印方法为修复受损热塑性塑料结构提供了高效、灵活的解决方案。DLfd-based inverse identification for heterogeneous composite properties under large-scale missing measurements with uncertainty quantificationYizhe Liu, Kuijian Yang, Yue Mei, Yuli Chen, Bin Dingdoi:10.1016/j.compositesa.2025.109123基于dlfd的不确定度定量非均质复合材料性能反演The inverse identification methods of heterogeneous mechanical properties from measured displacements/strains play a critical role in various engineering fields, ranging from aerospace to medical diagnostics. However, the commonly presence of large-scale measurement missingness significantly exacerbates the ill-posedness of the inverse problem. This dual challenge not only imposes critical limitations on the solution accuracy of conventional methods, but also creates growing requirements of effective uncertainty quantifications for the identification results. In this paper, a novel deep learning in frequency domain (DLfd)-based inverse identification framework is proposed to resolve large-scale and arbitrary distributed measurement missing scenarios. The framework transforms the inferred variables from high-dimensional discretized elastic properties to reduced missing displacement/strain components. This dimensionality reduction process effectively mitigates the challenges in solving the inverse problem and, most importantly, enables uncertainty quantification through the Bayesian inference method. Results demonstrate that even with more than 15% missing data, the L 1-error remains as low as 3.846%, and two standard deviation confidence intervals effectively encompass the ground truth, ensuring a reliable evaluation. Furthermore, the identification method is validated on phantom experiment data, successfully reconstructing both the position and shape of the inclusion, confirming the applicability of our framework in practical circumstances.从测量位移/应变反演非均质力学性能的方法在从航空航天到医学诊断等各个工程领域发挥着关键作用。然而,普遍存在的大规模测量缺失极大地加剧了逆问题的不适定性。这一双重挑战不仅严重限制了传统方法的求解精度,而且对鉴定结果的有效不确定度量化提出了越来越高的要求。本文提出了一种新的基于频域深度学习(DLfd)的反辨识框架,以解决大规模、任意分布的测量缺失场景。该框架将推断变量从高维离散弹性属性转换为减少缺失的位移/应变分量。这种降维过程有效地缓解了求解逆问题的挑战,最重要的是,可以通过贝叶斯推理方法对不确定性进行量化。结果表明,即使有超过15%的数据缺失,L 1-error保持在3.846%的低水平,两个标准差置信区间有效地包含了地面真实值,确保了可靠的评估。此外,在模拟实验数据上验证了识别方法,成功地重建了包裹体的位置和形状,验证了我们的框架在实际情况下的适用性。Decoding of contact number among carbon nanofibers in polymer composites: A new insight to govern electron transfer through tunneling zonesYasser Zare, Muhammad Naqvi, Kyong Yop Rheedoi:10.1016/j.compositesa.2025.109124聚合物复合材料中碳纳米纤维的接触数解码:通过隧道区控制电子转移的新见解The contact number between carbon nanofibers (CNFs) predominantly dictates the conductivity of composites; however, the specific parameters influencing the contact number remain unclear. In this paper, an equation is introduced to estimate the average contact number in CNF-filled samples (PCNFs), incorporating novel factors such as CNF concentration, percolation onset, CNF dimensions, curliness, interphase depth, network fraction, and tunneling characteristics (both distance and width). The contact number is computed and analyzed across various real-world samples. Furthermore, the proposed equation is validated by examining the effects of all relevant factors on the contact number. Notably, the contact number approaches zero when the tunneling diameter (d) is less than 7.5 nm or the tunneling distance (λ) exceeds 5.6 nm, but reaches a maximum of 250 at d = 40 nm and λ = 1 nm. This indicates that shorter tunneling distance and bigger contact diameter enhance the contact number. Additionally, the highest contact number of 76 occurs by a CNF radius (R) of 40 nm, while R = 100 nm combined with a CNF length of 30 μm drastically reduce the contact number to zero. Consequently, thinner and longer CNFs provide a higher contact number. Moreover, a lower percolation onset, thicker interphase, reduced CNF waviness, and greater network fraction further contribute to an increase in the contact number improving the PCNF conductivity.碳纳米纤维(CNFs)之间的接触数主要决定了复合材料的导电性;但是,影响联系号码的具体参数仍不清楚。在本文中,引入了一个方程来估计CNF填充样品(pcnf)的平均接触数,该方程结合了诸如CNF浓度、渗透开始、CNF尺寸、卷曲度、界面深度、网络分数和隧道特征(包括距离和宽度)等新因素。通过各种真实世界的样本计算和分析联系号码。此外,通过检查所有相关因素对联系号码的影响,验证了所提出的方程。值得注意的是,当隧穿直径(d)小于7.5 nm或隧穿距离(λ)大于5.6 nm时,接触数趋于零,而当d = 40 nm和λ = 1 nm时,接触数达到最大值250。这说明越短的隧道距离和越大的接触直径会增加接触数。此外,当CNF半径(R)为40 nm时,接触数最高为76,而R = 100 nm加上CNF长度为30 μm时,接触数大幅减少至零。因此,更薄和更长的cnf提供更高的接触数。此外,较低的渗透起始时间、较厚的界面相、较低的CNF波纹度和较大的网络分数进一步有助于增加接触数,从而提高PCNF的电导率。Composites Part B: EngineeringElastomer-modified perfluorocyclobutyl polymer/SiO2 composites for corrosion-resistant coatingsMark Rigel R. Ali, Reymark D. Maalihan, Eugene B. Caldonadoi:10.1016/j.compositesb.2025.112727 弹性体改性全氟环丁基聚合物/SiO2复合材料耐腐蚀涂层This study investigates the development of elastomer-modified perfluorocyclobutyl (E-PFCB) thermosetting composites containing polydimethylsiloxane (PDMS)-modified silica as nanofiller and exhibiting enhanced corrosion protection. Electrochemical impedance spectroscopy (EIS) results revealed that the incorporation of silica significantly improved the composite's corrosion resistance, with an impedance modulus (|Z|0.1 Hz) for the PFCB/silica composite containing 5% silica remaining above 106 Ω cm2 even over 30 d of immersion in a 3.5 wt% NaCl solution. This demonstrates the composite's superior ability to resist water uptake and electrolyte penetration. Potentiodynamic polarization scans showed a notable shift in corrosion potential (ECORR) from -700.2 mV for the unfilled E-PFCB to -101.1 mV for the 5% silica composite, indicating lowered tendency for corrosion. Mechanical testing further confirmed the improvements in the composite's properties, with hardness values increasing as silica loading increased. The 5% silica composite showed the highest hardness, reflecting the enhanced durability imparted by the silica particles. Thermomechanical analysis revealed a shift in the glass transition temperature (Tg) from 308 °C for the unfilled E-PFCB to 330 °C upon the addition of 5% silica. In addition, water contact angle measurements confirmed the hydrophobic nature of the composites, with contact angles consistently above 90°, further limiting water interaction and corrosion risk. Hence, the use of PDMS-modified silica as a nanofiller in crosslinked E-PFCB composites significantly enhances both corrosion resistance and thermomechanical properties, making these composites suitable for applications in harsh environments. These findings open up an opportunity for the development of new and advanced protective coatings for many practical applications.本研究研究了弹性体改性全氟环丁基(E-PFCB)热固性复合材料的发展,该复合材料含有聚二甲基硅氧烷(PDMS)改性二氧化硅作为纳米填料,并具有增强的防腐性能。电化学阻抗谱(EIS)结果表明,二氧化硅的掺入显著提高了复合材料的耐腐蚀性,含有5%二氧化硅的PFCB/二氧化硅复合材料在3.5 wt% NaCl溶液中浸泡30 d后,阻抗模量(|Z|0.1 Hz)仍高于106 Ω cm2。这表明复合材料具有优异的抗吸水和抗电解质渗透能力。动电位极化扫描显示,腐蚀电位(ECORR)从未填充的E-PFCB的- 7002 mV显著变化到5%二氧化硅复合材料的-101.1 mV,表明腐蚀倾向降低。力学测试进一步证实了复合材料性能的改善,硬度值随着二氧化硅载荷的增加而增加。5%二氧化硅复合材料的硬度最高,反映了二氧化硅颗粒增强的耐久性。热力学分析表明,加入5%二氧化硅后,未填充的E-PFCB的玻璃化转变温度(Tg)从308°C转变为330°C。此外,水接触角测量证实了复合材料的疏水性,接触角始终大于90°,进一步限制了水的相互作用和腐蚀风险。因此,在交联E-PFCB复合材料中使用pdms改性二氧化硅作为纳米填料,可显著提高其耐腐蚀性和热机械性能,使这些复合材料适用于恶劣环境。这些发现为许多实际应用开发新的和先进的保护涂层开辟了一个机会。Impact Efficacy of Sandwich Structures with Additively Manufactured Skins and Elastomeric Foam CoresSean Eckstein, George Youssefdoi:10.1016/j.compositesb.2025.112728增材制造外皮和弹性泡沫芯夹层结构的冲击性能Sandwich structures are ubiquitous in various applications due to their superior specific properties, attracting assiduous research under a broad range of loading conditions. Introducing additive manufacturing (3D printing) of composite skins and considering novel elastomeric core materials necessitate exploring the process-property interrelationship with emphasis on impact loading. Therefore, this research study aims to elucidate the impact efficacy of additively manufactured sandwich structures, hinging on 3D-printed skins using continuous carbon fiber polymer matrix composites. The 3D-printed skins are adhered to polyurea foam cores with superior impact efficacy and remarkable recoverability. One sample set was subjected to low-velocity impacts using an instrumented drop tower at 4.43 m/s, and another separate set was submitted to moderate-velocity impacts using a small-scale shock tube at 15 m/s. All mechanical testing was accompanied by high-speed digital image correlation (DIC) to elucidate the whole field kinematic variables. The specimens were impacted under various testing parameters, including the size of the hemispherical impactor, sample configuration, mounting plate configuration, and impact velocity, to probe their dynamic behavior. The impact and deformation characteristics, including force-time, axial strain-time, and dynamic and permanent back-surface displacement signatures, were deduced from a high-fidelity force sensor, high-speed and high-resolution DIC, and a laser displacement sensor, and thoroughly analyzed to understand the efficacy of the newly designed sandwich structures. Reconstructive optical microscopy revealed the damage and failure that the structures endured. Across all sample configurations and testing parameters, the structures yielded an energy absorption of ∼91% of the input impact energy, exemplifying impact mitigation capabilities ideal for protective sports gear and structural components in aerospace, automotive, and defense applications.夹层结构由于其优越的特殊性能在各种应用中无处不在,在广泛的载荷条件下引起了人们的不懈研究。引入增材制造(3D打印)复合材料蒙皮,并考虑新型弹性体芯材,需要探索工艺性能之间的相互关系,重点是冲击载荷。因此,本研究旨在阐明增材制造的三明治结构,铰接在3d打印皮肤上使用连续碳纤维聚合物基复合材料的冲击效果。3d打印皮肤粘附在聚脲泡沫芯上,具有优异的冲击效能和显著的可恢复性。其中一组样本以4.43米/秒的速度使用仪器降落塔进行低速冲击,另一组样本则以15米/秒的速度使用小型激波管进行中速冲击。所有力学测试都伴随着高速数字图像相关(DIC)来阐明整个场的运动学变量。在半球形冲击器的尺寸、试样结构、安装板结构和冲击速度等参数下对试样进行冲击,探讨其动力学行为。利用高保真力传感器、高速高分辨率DIC和激光位移传感器,分析了夹层结构的冲击和变形特性,包括力时间、轴向应变时间、动态和永久后表面位移特征,并对其进行了深入分析,以了解新设计的夹层结构的有效性。重建光学显微镜显示了结构所承受的损伤和破坏。在所有样品配置和测试参数中,结构产生的能量吸收为输入冲击能量的91%,证明了冲击缓解能力是航空航天,汽车和国防应用中防护运动装备和结构部件的理想选择。Effects of Axial Load on Torsional Fatigue of 3D Braided Carbon Fiber Composites: Mechanisms and Life PredictionJikang Li, Zheng Liu, Yuanwen Liu, Zhe Zhang, Xu Chendoi:10.1016/j.compositesb.2025.112732 轴向载荷对三维编织碳纤维复合材料扭转疲劳的影响:机理与寿命预测Three dimensional braided carbon fiber reinforced epoxy composites are gradually replacing traditional materials in transmission components. This study experimentally investigates the influence of axial loads on torsional fatigue damage evolution and lifetime by integrating three dimensional digital image correlation, acoustic emission monitoring, and micro-computed tomography analysis. A fatigue life prediction model incorporating axial load effects is subsequently established. Results indicate that axial loads significantly modify the torsional fatigue behavior of 3D braided composites by redistributing local strain and altering damage progression. Under 0 MPa axial load, the material exhibited a fatigue life of 2787 cycles. Compressive axial loading (-40 MPa) reduced torsional fatigue life by 47% compared to the no-axial-load condition, accelerating stiffness deterioration. In contrast, tensile axial loading (40 MPa) extended the fatigue life to 5007 cycles by suppressing interface debonding propagation. DIC analysis revealed that compressive loading induced a three-stage strain accumulation in resin-rich regions. Tensile loading maintained strain field stability through stress redistribution. Combined AE and Micro-CT analysis demonstrated that compressive loading increased the matrix cracking proportion to 84%, expanded post-failure crack volume by 38%, and formed spiral divergent damage zones. Tensile loading constrained the damage zone width to 7.6 mm and reduced the interface debonding energy proportion. Finally, a multiaxial fatigue life prediction model accounting for mean stress effects induced by axial loads was developed based on microscopic damage mechanisms. The model successfully addresses combined axial-torsional loading effects in 3D braided composites. Experimental validation confirmed that all predicted results fell within the two-fold scatter band.三维编织碳纤维增强环氧复合材料正在逐步取代传统的传动部件材料。通过三维数字图像相关、声发射监测和微计算机断层扫描分析,研究轴向载荷对扭转疲劳损伤演化和寿命的影响。建立了考虑轴向载荷影响的疲劳寿命预测模型。结果表明,轴向载荷通过重新分配局部应变和改变损伤进程,显著改变了三维编织复合材料的扭转疲劳行为。在0 MPa轴向载荷下,材料的疲劳寿命达到2787次。与无轴向载荷相比,轴向压缩载荷(-40 MPa)使扭转疲劳寿命降低了47%,加速了刚度的退化。相反,拉伸轴向加载(40 MPa)通过抑制界面脱粘扩展,使疲劳寿命延长至5007次。DIC分析显示,压缩加载在富树脂区诱发了三阶段应变积累。拉伸载荷通过应力重分布维持应变场稳定。AE和Micro-CT联合分析表明,压缩载荷使基体开裂比例增加到84%,破坏后裂纹体积扩大了38%,并形成螺旋形发散损伤区。拉伸载荷使损伤区宽度限制在7.6 mm,降低了界面脱粘能比例。最后,基于细观损伤机理,建立了考虑轴向载荷平均应力效应的多轴疲劳寿命预测模型。该模型成功地解决了三维编织复合材料的轴扭复合载荷效应。实验验证证实,所有预测结果都落在两倍散射带内。A new equivalent crack length technique for mode I fracture of adhesively bonded jointsAli Shivaie Kojouri, Javane Karami, Jialiang Fan, Akash Sharma, Anastasios P. Vassilopoulos, Veronique Michaud, Wim Van Paepegem, Danny Van Hemelrijck, Kalliopi-Artemi Kalteremidoudoi:10.1016/j.compositesb.2025.112733黏合接头I型断裂的等效裂纹长度新技术The current investigation introduces the concepts of the equivalent crack length approach for thin and thick adhesive joints. Its applicability is assessed for adhesively bonded composite and steel joints with a bondline thickness ranging from 0.4mm to 10 mm. To achieve this objective, the equivalent crack length method is formulated utilizing a beam on elastic foundation model. A series of experiments were performed utilizing various loading rates and geometries, and the energy release rate of the thick adhesive joints was determined through beam on elastic foundation model using the crack length values obtained both experimentally and through the equivalent crack length technique. In general, the energy release rate calculated using the equivalent crack length approach and crack length measured experimentally yield comparable results for all tested specimens. For side-grooved specimens with steady crack propagation, the average calculation error of the energy release rate obtained from the experimentally measured crack length experimentally and the equivalent crack length approach is less than seven and six percent for low and high loading rates, respectively. The proposed equivalent crack length method facilitates the experimental fracture characterization of adhesive joints since it eliminates the need for tedious crack length measurements during the test.本研究引入了薄厚粘接等效裂缝长度法的概念。评估其适用于粘合线厚度为0.4mm ~ 10 mm的复合材料和钢连接。为实现这一目标,采用弹性地基梁模型,建立了等效裂缝长度法。在不同加载速率和几何形状下进行了一系列试验,利用实验和等效裂缝长度技术得到的裂缝长度值,确定了弹性基础模型上的厚粘接节点的能量释放率。一般来说,用等效裂纹长度法计算的能量释放率和实验测量的裂纹长度对所有试件的结果都是相当的。对于裂纹扩展稳定的边槽试件,在低加载率和高加载率条件下,采用实验测量裂纹长度法和等效裂纹长度法计算能量释放率的平均误差分别小于7%和6%。所提出的等效裂缝长度方法消除了测试过程中繁琐的裂缝长度测量,有助于粘结接头断裂的实验表征。Enhanced aramid fiber epoxy resin composites insulation properties via π-π stacking driven ZnONW heterojunction growth to reconstruct aramid fiber surfaceGuowei Xia, Jun Xie, Bobin Xu, Xiaoyu Shi, Ping Huang, Yan Li, Qing Xiedoi:10.1016/j.compositesb.2025.112729通过π-π堆叠驱动ZnONW异质结生长重建芳纶纤维表面,增强芳纶纤维环氧树脂复合材料的绝缘性能The Gas-insulated switchgear (GIS) is the core component in the development of China’s new ultra-high voltage power system. Its key part, the insulation pull rod, needs to withstand substantial mechanical loads and impact voltages. The poor compatibility between aramid fiber and epoxy resin is the key problem that affects the insulation performance of pull rods. This paper proposes a method to reconstruct the surface of aramid fibers by utilizing the π-π stacking of iron phthalocyanine (FePc) and the heterojunction growth of zinc oxide nanowires (ZnONW). This approach roughens the fiber surface and improves compatibility, effectively enhancing the insulation performance of aramid fiber-epoxy resin composites. The characterization techniques such as ultraviolet photoelectron spectroscopy (UPS) confirm the π-π stacking effect of FePc and its formation of a heterojunction with ZnO. The insulation performance tests indicate that with a growth concentration of 100 mM and a growth time of 2 h, the aramid fiber-epoxy resin composite exhibits optimal insulation properties. Under these conditions, the breakdown voltage increased by 73.02%, and the breakdown electric field strength improved by 72.13%. Molecular dynamics (MD) simulations and density functional theory (DFT) analyses reveal the π-π stacking process and the mechanisms behind the enhanced insulation properties.气体绝缘开关柜(GIS)是中国新型超高压电力系统发展的核心部件。它的关键部分,绝缘拉杆,需要承受大量的机械负荷和冲击电压。芳纶纤维与环氧树脂相容性差是影响拉杆绝缘性能的关键问题。本文提出了一种利用酞菁铁(FePc)的π-π堆叠和氧化锌纳米线(ZnONW)的异质结生长来重建芳纶纤维表面的方法。这种方法使纤维表面变得粗糙,提高了相容性,有效地提高了芳纶纤维-环氧树脂复合材料的绝缘性能。紫外光电子能谱(UPS)等表征技术证实了FePc的π-π堆积效应及其与ZnO形成异质结。绝缘性能试验表明,当生长浓度为100 mM,生长时间为2 h时,芳纶纤维-环氧树脂复合材料的绝缘性能最佳。在此条件下,击穿电压提高了73.02%,击穿电场强度提高了72.13%。分子动力学(MD)模拟和密度泛函理论(DFT)分析揭示了π-π堆积过程和增强绝缘性能背后的机制。来源:复合材料力学仿真Composites FEM

未登录
还没有评论
课程
培训
服务
行家
VIP会员 学习计划 福利任务
下载APP
联系我们
帮助与反馈