今日更新:Composite Structures 4 篇,Composites Part B: Engineering 6 篇,Composites Science and Technology 1 篇
Nonlocal modeling of transient heat conduction in anisotropic functionally graded materials by using peridynamic operator method
Yifan Qian, Zhiyuan Li, Dan Huang
doi:10.1016/j.compstruct.2025.119815
基于周动力学算子的各向异性功能梯度材料瞬态热传导非局部建模
Functionally graded materials (FGMs) are widely used in engineering fields due to their exceptional properties, particularly in high-temperature environments, and they typically exhibit anisotropic characteristics. Peridynamic operator method (PDOM) can transform the local differential or its product form into a nonlocal integral form, thereby constructing nonlocal models for a variety of physical problems. This paper proposes a nonlocal model for transient heat conduction in anisotropic FGMs by using PDOM. The energy functional of the anisotropic FGMs heat conduction equation is established by applying the variational an alysis. The nonlocal transient equation is derived from classical the local differential forms of energy functional employing PDOM. The applicability of the proposed model is validated through implementing several numerical examples, including transient heat conduction problems for hole-containing, and cracked structures of isotropic, orthotropic and anisotropic FGMs under various boundary conditions.
功能梯度材料(fgm)由于其特殊的性能,特别是在高温环境下,被广泛应用于工程领域,它们通常表现出各向异性特性。动态算子法(PDOM)可以将局部微分或其乘积形式转化为非局部积分形式,从而构建各种物理问题的非局部模型。本文提出了一种基于PDOM的各向异性fgm瞬态热传导非局部模型。应用变分分析方法,建立了各向异性fgm热传导方程的能量泛函。利用PDOM从经典能量泛函的局部微分形式导出了非局部瞬态方程。通过不同边界条件下各向同性、正交异性和各向异性fgm含孔和裂纹结构的瞬态热传导问题,验证了该模型的适用性。
A Dougong-inspired metamaterial for three-directional low-frequency vibration isolation and broad bandgaps
Jingxu Liu, Yansen Wu, Yongtao Sun, Qun Yan, Anshuai Wang, Yunxiang Ma, Hao Yan, Getachew D. Aylew, Castor N. Mwankefu, Qian Ding
doi:10.1016/j.compstruct.2025.119818
一种受斗拱启发的三向低频隔振宽频带材料
Achieving both low-frequency vibration isolation and high load-bearing capacity remains a significant challenge in traditional vibration isolator design, particularly for multi-directional applications. The research presents a novel metamaterial vibration isolator inspired by the Dougong structure in traditional Chinese architecture. The Dougong structure exhibits exceptional integrated performance in both load-bearing capacity and vibration damping. By leveraging its unique deformation mechanis ms, the proposed design successfully achieves simultaneous multi-directional vibration isolation and structural load-bearing. The key innovation lies in the Quasi-Zero Stiffness response achieved through controlled deformation of the Gong element, which enables broadband low-frequency vibration isolation while maintaining mechanical stability. Numerical simulation and experimental results confirm that this structure has effective low-wideband vibration isolation characteristics. This research establishes a novel paradigm for the design of multifunctional vibration isolation metamaterials, thereby advancing the development of multi-directional vibration isolators with enhanced load-bearing capabilities.
在传统的隔振器设计中,实现低频隔振和高承载能力仍然是一个重大挑战,特别是在多向应用中。本研究以中国传统建筑中的斗拱结构为灵感,提出一种新型的超材料隔振器。斗拱结构在承载能力和减振能力方面表现出优异的综合性能。利用其独特的变形机制,该设计成功地同时实现了多向隔振和结构承重。关键的创新在于通过控制Gong元件的变形实现准零刚度响应,从而在保持机械稳定性的同时实现宽带低频振动隔离。数值模拟和实验结果证实了该结构具有有效的低宽带隔振特性。本研究为多功能隔振超材料的设计建立了一种新的范式,从而推动了具有增强承载能力的多向隔振器的发展。
A data-driven method for constitutive-model-free multiscale concurrent an alysis: theoretical modeling and numerical simulation
Ji He, Shengda Jiang, Cong Guo
doi:10.1016/j.compstruct.2025.119830
无本构模型多尺度并行分析的数据驱动方法:理论建模与数值模拟
Investigations into the macroscopic behavior of materials with complex microstructures are critical for both mechanics and materials science. One of the most significant challenges is the difficulty of developing a constitutive model. In this study, a mechanistically informed, data-driven, and constitutive-model-free method is developed to predict the mechanical response of general heterogeneous materials under complex deformation. The proposed method includes the development of a data-driven computing solver for micromechanical systems that is valid for any local constitutive behavior, which allows lower-scale stress–strain data to be used for predicting the upper-scale mechanical behavior under the two-way coupling concept. The proposed method establishes the minimization of a new distance function for the dataset of all material phases, subject to the constraints introduced by the conservation laws of micromechanical systems. We demonstrate the application of the developed data-driven computational solver in predicting the mechanical behavior of fiber reinforced materials. We show that, as the material dataset increasingly closely approximates a classical material law in phase space, the data-driven solutions converge to the phenomenological model solutions. Additionally, we demonstrate the robustness of the data-driven solver by combining it with the finite element method under complex loading conditions. The interpolated and accelerated data search method was also investigated using the locally convex construction and tree search algorithm, which achieves computational efficiency comparable to phenomenological models with satisfactory agreement.
研究具有复杂微观结构的材料的宏观行为对力学和材料科学都是至关重要的。最重要的挑战之一是开发本构模型的困难。在这项研究中,开发了一种力学信息,数据驱动和无本构模型的方法来预测复杂变形下一般非均质材料的力学响应。所提出的方法包括开发一种数据驱动的微力学系统计算求解器,该求解器适用于任何局部本构行为,允许在双向耦合概念下使用低尺度应力-应变数据来预测高尺度力学行为。该方法在微机械系统守恒定律的约束下,为所有材料相的数据集建立了一个新的距离函数的最小化。我们演示了开发的数据驱动计算求解器在预测纤维增强材料力学行为中的应用。我们表明,随着材料数据集越来越接近相空间中的经典材料定律,数据驱动的解决方案收敛于现象学模型解决方案。此外,通过将数据驱动求解器与有限元方法相结合,验证了数据驱动求解器在复杂载荷条件下的鲁棒性。利用局部凸构造和树搜索算法研究了插值和加速数据搜索方法,计算效率与现象学模型相当,一致性较好。
Novel surface-attached resonant acoustic metamaterials for vibration and noise reduction in the natural gas pipeline
Jingjian Xu, Hanjie Yang, Junli Chen, Dan Sui, Jie Zhou, Heye Xiao, Xinghong Xiang, Lei Chen
doi:10.1016/j.compstruct.2025.119831
用于天然气管道减振降噪的新型表面附着共振声学超材料
This study proposes a novel surface-attached resonant acoustic metamaterial (SRAM) for natural gas pipelines to reduce structural vibration and radiated noise. Guided by measured pipeline spectra that identify dominant frequency peaks, the design leverages a synergistic combination of resonance and damping to enhance vibration and noise control. The SRAM preserves the original pipeline structure, enabling easy installation and seamless integration into existing systems. The vibration-mitigation mechanis m and the specific functions of the SRAM components were elucidated through unit cell modeling and acoustic-structural coupling ana lysis. On-site experiments were conducted on a pipeline with a flow rate of 120,000 Nm3/h. The results showed a maximum reduction of approximately 4.3 dB in vibration level across the test frequency range and a maximum sound pressure level reduction of approximately 8.2 dB at the peak frequency. Microphone-array beamforming techniques further validated the noise reduction efficiency at the peak frequencies of 1250 Hz and 1823 Hz. Additional tests under varying flow rates confirmed the robustness of the SRAM. This study demonstrates that the proposed acoustic metamaterial provides a practical, effective, and reliable solution for pipeline vibration and noise control in industrial applications.
提出了一种新型的表面附着共振声学超材料(SRAM),用于减少天然气管道的结构振动和辐射噪声。该设计以测量的管道频谱为指导,识别主频率峰值,利用共振和阻尼的协同组合来增强振动和噪声控制。SRAM保留了原有的管道结构,便于安装和无缝集成到现有系统中。通过单元胞模型和声-结构耦合分析,阐明了SRAM组件的减振机理和具体功能。现场实验在流量为120,000 Nm3/h的管道上进行。结果表明,在整个测试频率范围内,振动级最大降低约4.3 dB,峰值频率处声压级最大降低约8.2 dB。麦克风阵列波束形成技术进一步验证了峰值频率为1250 Hz和1823 Hz的降噪效率。在不同流速下的额外测试证实了SRAM的稳健性。研究表明,所提出的声学超材料为工业应用中的管道振动和噪声控制提供了一种实用、有效和可靠的解决方案。
Hierarchical Damage Mechanis ms and Multiscale Tensile Property Prediction of Woven Bamboo Strips and Their Epoxy-based Composites
Yaocheng Wang, Hongfeng Luo, Chuanfu Chen, Yinliang Zhang, Qi Fan, Xiaolong Hao, Liping Li, Chuigen Guo, Rongxian Ou, Qingwen Wang
doi:10.1016/j.composites b.2025.113170
竹编带及其环氧基复合材料的分层损伤机理及多尺度拉伸性能预测
The application potential of bamboo in composite materials is well-established; however, significant performance variations among bamboo units and inherent structural uncertainties in plain-woven multiscale composites pose critical challenges. To enable precise prediction of tensile properties, this study conducts comprehensive micro- and macro-scale a nalyses of woven bamboo strips (WBS) reinforcements and their single- and multi-layer composites (WBC) across different radial positions. Addressing the limitations in prediction accuracy caused by complex stress distributions and multiscale characteristics within damage zones during tensile loading, we propose a novel multiscale model for WBC. This model integrates strain-based digital image correlation (DIC) techniques to predict and ana lyze damage initiation and evolution in both mesoscopic reinforcements (vascular bundles, VB) and macroscopic composites. Results demonstrate that WBS achieve a maximum tensile strength of 330 MPa, while WBC exhibit a peak tensile strength of 120 MPa. The linear fracture behavior of these composites exhibits hierarchical relationships between internal structures and tensile properties. Experimental and simulation results show excellent agreement, validating the reliability of this multiscale prediction strategy for investigating the mechanical responses of WBS at multiple scales and elucidating the damage mechanis ms of WBC. Finally, through precise calculation of the effective reinforcement fiber volume fractions in fabrics and composites, we demonstrate that the enhanced Rule of Mixtures (ROM) model significantly enhances the accuracy and efficiency tensile property predictions for WBC (error < 10%).
竹材在复合材料中的应用潜力已得到充分肯定;然而,竹单元之间的显著性能差异和平纹编织多尺度复合材料固有的结构不确定性构成了关键的挑战。为了准确预测竹编增强材料的拉伸性能,本研究在不同径向位置对竹编增强材料及其单层和多层复合材料进行了微观和宏观的综合分析。针对拉伸加载过程中损伤区域内复杂的应力分布和多尺度特征对预测精度的限制,提出了一种新的WBC多尺度模型。该模型集成了基于应变的数字图像相关(DIC)技术,用于预测和分析细观增强材料(维管束,VB)和宏观复合材料的损伤发生和演变。结果表明,WBS的最大抗拉强度为330 MPa,而WBC的峰值抗拉强度为120 MPa。这些复合材料的线性断裂行为表现出内部结构与拉伸性能之间的层次关系。实验结果与仿真结果吻合良好,验证了该多尺度预测策略在研究WBS多尺度力学响应和阐明WBS损伤机理方面的可靠性。最后,通过对织物和复合材料中有效增强纤维体积分数的精确计算,我们证明了增强的混合规则(ROM)模型显著提高了WBC拉伸性能预测的准确性和效率(误差< 10%)。
Ablation behavior of coating-matrix integrated C/C–SiC-HfC-ZrC composites in plas ma wind tunnel
Sijie Kou, Xian Liu, Shaobo Yang, Chun Guo, Shangwu Fan, Juanli Deng
doi:10.1016/j.composites b.2025.113178
涂层-基体集成C/C - sic - hfc - zrc复合材料在等离子体风洞中的烧蚀行为
Coating-matrix integrated C/C–SiC-HfC-ZrC composites were fabricated via RMI using HfSi2-ZrSi2 hybrid alloys and slurry brushing. The composite featured a borosilicate glass outer layer and a continuous in-situ (Zr, Hf)Si2-(Hf, Zr)C–SiC coating integrated with the matrix. In a plas ma wind tunnel at 5.0 MW/m2 and 7.0 kPa, the composite exhibited a linear ablation rate of −2.30 × 10−3 mm/s and a mass ablation rate of 4.90 × 10−4 g/s. The coating debonded from the substrate during ablation caused by thermal mis match and the escape of gaseous products, but effectively blocked heat, flow, and oxygen, protecting the substrate. Surface (Hf, Zr)O2 densified via quasi-liquid-phase sintering, with liquid-phase dissipation, temperature surge, and transverse crack inside coating formation. Gaseous product evolution, SiO2 flow, and temperature gradients promoted columnar (Hf, Zr)O2 growth, retarding atomic oxygen erosion. Under harsher conditions (6.0 MW/m2, 9.0 kPa), the surface temperature exceeded 2800 °C, causing oxide melting, coating degradation, and severe substrate oxidation.
采用HfSi2-ZrSi2复合合金和浆液涂刷,通过RMI法制备了涂层基集成C/C - sic - hfc - zrc复合材料。该复合材料具有硼硅酸盐玻璃外层和与基体集成的连续原位(Zr, Hf)Si2-(Hf, Zr) C-SiC涂层。在5.0 MW/m2和7.0 kPa的等离子体风洞中,复合材料的线性烧蚀速率为- 2.30 × 10−3 mm/s,质量烧蚀速率为4.90 × 10−4 g/s。在烧蚀过程中,由于热失配和气体产物的逸出,涂层从基材上脱落,但有效地阻挡了热量、流动和氧气,保护了基材。表面(Hf, Zr)O2通过准液相烧结致密化,存在液相耗散、温度骤升、涂层内部形成横向裂纹等现象。气态产物演化、SiO2流动和温度梯度促进了柱状(Hf, Zr)O2生长,延缓了原子氧侵蚀。在更恶劣的条件下(6.0 MW/m2, 9.0 kPa),表面温度超过2800℃,导致氧化物熔化、涂层降解和衬底严重氧化。
Bio-inspired suture interface for enhancing strength and damage tolerance of repaired composite laminates under tensile and bending tests
Yuan Li, Xianhe Cheng, Jing Yan, Zhongyuan Shi, Hexuan Shi, Rundong Ding, Junwei Sun, Deyu Yue, Qigang Han
doi:10.1016/j.composites b.2025.113163
在拉伸和弯曲试验中增强修复复合材料层合板的强度和损伤容忍度的仿生缝合界面
Adhesively bonded step repairs are widely employed in aerospace applications to restore the structural integrity of damaged composite components while preserving a s mooth aerodynamic profile. However, the stiffness mis match between the adherend and the adhesive results in a weak repair interface for load transfer, predisposing traditional adhesively bonded step repairs to debonding and catastrophic failure. Herein, inspired by the interlocking structure found in the elytra of the ironclad beetle, this study proposes an innovative suture interface step repair (SISR) laminate. Fabricated via vacuum bag technique, the SISR integrates optimized fiber orientation with a unique interlocking interface to enhance mechanical performance. Afterwards, Experimental evaluation through quasi-static tensile and three-point bending tests compared three repair configurations: traditional circular step repair (TCSR), fiber-oriented step repair (FOSR), and SISR. Finite element an alysis was further conducted to elucidate the underlying damage mechanis ms. Remarkably, the results demonstrated that the SISR laminate achieved a peak force increase of 30.47% and 6.94% relative to TCSR and FOSR in tensile testing, with corresponding improvements of 8.65% and 2.94% observed in three-point bending tests. In fact, these enhancements stem from the optimized fiber orientation reducing parent laminate removal and the suture interlocking interface effectively mitigating damage concentration by extending crack propagation distance. This research presents a novel approach for advancing the repair of lightweight aerospace components, offering significant potential for improved durability and reliability.
粘接修复在航空航天应用中广泛应用于修复受损复合材料部件的结构完整性,同时保持其光滑的气动外形。然而,黏合剂和胶粘剂之间的刚度不匹配导致修复界面弱,从而导致传统的黏合剂粘合步骤修复出现脱粘和灾难性失效。在此,受铁甲甲虫鞘翅中发现的互锁结构的启发,本研究提出了一种创新的缝合界面台阶修复(SISR)层叠板。通过真空袋技术制造,SISR集成了优化的纤维取向和独特的联锁界面,以提高机械性能。随后,通过准静态拉伸和三点弯曲试验对三种修复结构进行了实验评估:传统的圆形台阶修复(TCSR)、纤维定向台阶修复(FOSR)和SISR。进一步进行了有限元分析,以阐明潜在的损伤机制。结果表明,与TCSR和FOSR相比,SISR层合板在拉伸试验中的峰值力分别提高了30.47%和6.94%,在三点弯曲试验中分别提高了8.65%和2.94%。事实上,这些增强源于优化的纤维取向减少了母层的去除,缝线互锁界面通过延长裂纹扩展距离有效地减轻了损伤集中。这项研究为推进轻型航空部件的修复提供了一种新方法,为提高耐久性和可靠性提供了巨大的潜力。
The influence of microstructure of carbon fiber on the compressive strength of its composite materials
Xinfeng Ouyang, Shuo Duan, Qiufei Chen, Guojie Ge, Dong Liu, Kang Lin, Guo Li, Fen Wang, Yunpeng Liu, Yen Wei, Kangmin Niu
doi:10.1016/j.composites b.2025.113166
碳纤维微观结构对复合材料抗压强度的影响
This study systematically investigates the evolution of carbon fiber microstructure within the 1500-2400 °C temperature range and its influence on mechanical properties, addressing the key scientific challenge of controlling the compressive performance of carbon fiber composites in industrial production. By integrating multi-scale microstructural characterization—including X-ray diffraction (XRD), Raman spectroscopy, s mall-angle X-ray scattering (SAXS), and trans mission electron microscopy (TEM)—with mechanical testing of both the carbon fibers and their composites, 2200 °C was identified as a critical graphitization-sensitive temperature. Below this temperature (from 1500 °C to 2100 °C), structural evolution is primarily driven by the removal of non-carbon elements and the proliferation of crystalline regions. The crystallite size growth rate was higher in the La direction than in the Lc direction, increasing by 90.7% and 64.3%, respectively, while the degree of crystallite orientation and the degree of graphitization progressively increased. The orientation of internal micropores increased synergistically, and a decrease in the micropore axial ratio indicated that the elongated micropores gradually became "fatter". Above this temperature (from 2100 °C to 2400 °C), the evolution is dominated by the three-dimensional reconstruction of crystalline regions. The growth rate of crystallite size in the La direction was lower than in the Lc direction (3.5% and 4.6%, respectively), with the overall growth rate slowing significantly. The R-value, indicating the degree of graphitization, dropped sharply from 0.9052 to 0.7471, suggesting that structural reconstruction accelerates after the sensitive temperature is passed. The orientation of both crystalline regions and micropores showed a s mall, synergistic increase. The evolution of the microstructure directly impacts the mechanical properties of the carbon fibers and their composites. As the temperature was increased from 1500 °C to 2400 °C, the modulus of the fibers and composites increased while their tensile strength decreased. The single-filament compressive strength decreased by 31.3%, and the 0° composite compressive strength, open-hole compression (OHC) strength, and compression-after-impact (CAI) strength decreased by 17.3%, 21.2%, and 51.3%, respectively. An ana lysis of the composite compression failure morphology shows that the enhanced degree of graphitization, enlarged crystallite size, and the formation of ribbon-like structures at grain boundaries lead to the disruption of cross-linking structures and tie-points, which diminishes the capacity to resist tensile and bending deformations. This research quantitatively elucidates the relationship between the heat-treatment-controlled microstructural evolution of carbon fibers and the compressive performance of their composites, providing theoretical guidance and a practical basis for the industrial production of carbon fibers with enhanced compressive performance.
本研究系统研究了1500-2400℃温度范围内碳纤维微观结构的演变及其对力学性能的影响,解决了工业生产中碳纤维复合材料压缩性能控制的关键科学难题。通过综合多尺度微观结构表征——包括x射线衍射(XRD)、拉曼光谱、小角度x射线散射(SAXS)和透射电子显微镜(TEM)——以及碳纤维及其复合材料的力学测试,2200℃被确定为石墨化的关键敏感温度。低于这个温度(从1500°C到2100°C),结构演变主要是由非碳元素的去除和晶体区域的增殖驱动的。晶粒尺寸在La方向上的增长速率高于Lc方向,分别增长了90.7%和64.3%,晶粒取向度和石墨化度逐渐提高。内部微孔的取向协同增加,微孔轴向比减小表明拉长的微孔逐渐“变胖”。 在此温度(2100℃至2400℃)以上,晶体区域的三维重构是主要的演化过程。La方向晶粒尺寸的增长速度低于Lc方向(分别为3.5%和4.6%),整体增长速度明显放缓。表征石墨化程度的r值从0.9052急剧下降到0.7471,表明过敏感温度后结构重构加速。结晶区和微孔的取向都表现出微小的协同增加。 微观结构的演变直接影响碳纤维及其复合材料的力学性能。当温度从1500℃升高到2400℃时,纤维和复合材料的模量增加,抗拉强度下降。单丝抗压强度下降31.3%,0°复合抗压强度、裸眼抗压(OHC)强度和冲击后抗压(CAI)强度分别下降17.3%、21.2%和51.3%。对复合材料压缩破坏形貌的分析表明,石墨化程度的增强、晶粒尺寸的增大以及晶界处带状结构的形成导致交联结构和连接点的破坏,从而降低了复合材料抗拉伸和弯曲变形的能力。本研究定量阐明了热处理控制的碳纤维微观组织演变与其复合材料抗压性能之间的关系,为抗压性能增强碳纤维的工业化生产提供理论指导和实践依据。
Constructing atomic-level heterointerface in oxygen vacancy-tunable ZnO/CuO heterojunction to boost charge separation and transfer
Yu Zhang, Xiaoli Jin, Jingwen Meng, Hao Chen, Yunrui Huang, Qingfan Meng, Yiting Wang, Yanjie Fu, Xiaodi Liu, Jianmin Ma
doi:10.1016/j.composites b.2025.113167
在氧空位可调ZnO/CuO异质结中构建原子级异质界面以促进电荷分离和转移
Driven by random charge movement and Coulombic force, the photogenerated electron-hole pairs in photocatalysts tend to rapidly recombine, severely limiting their application. Atomic-level heterointerface engineering and oxygen vacancies (Ov) modulation hold tremendous potential in promoting charge separation and transfer. A series of S-scheme Ov-ZnO/CuO heterojunctions are in situ synthesized via a solvothermal method followed by calcination using bimetallic Zn/Cu-MOF as precursors. The atomic distances between O atoms in the ZnO (002) facet closely match those between Cu atoms in the CuO (-220) facet (5.76 vs. 5.80 Å), while Zn2+ and Cu2+ have similar ionic radii (0.74 vs. 0.73 Å). The structural compatibility enables the formation of Zn-O-Cu bonds at the tightly integrated ZnO/CuO interface, thus achieving atomic-level heterointerface. Owing to the unique structure of the precursors, Ov-ZnO/CuO form into hierarchical porous microspheres that are composed of ultras mall nanocrystals. In addition, the Ov content of Ov-ZnO/CuO is tuned by changing the Cu:Zn molar ratios of the precursors. The S-scheme charge transfer mechanis m reveals that the synergistic effect of atomic-level heterointerface, suitable Ov content, CuO-derived photothermal effect, and short charge diffusion distance effectively promotes the charge separation and transfer in Ov-ZnO/CuO-10%, ultimately achieving a superior CO production rate of 9.13 μmol g-1 h-1 with 93.7% retention after four cycles. This study offers an effective route to enhance photocatalytic CO2 reduction activity and sheds new light on purposeful design of heterojunctions based on the structural characteristics of components.
在随机电荷运动和库仑力的驱动下,光催化剂中产生的电子-空穴对具有快速复合的特点,严重限制了其应用。原子级异质界面工程和氧空位(Ov)调制在促进电荷分离和转移方面具有巨大的潜力。以双金属Zn/Cu-MOF为前驱体,采用溶剂热法原位合成了一系列S-scheme Ov-ZnO/CuO异质结。ZnO(002)面中O原子之间的原子距离与CuO(-220)面中Cu原子之间的原子距离非常接近(5.76 vs. 5.80 Å),而Zn2+和Cu2+具有相似的离子半径(0.74 vs. 0.73 Å)。结构相容性使得在紧密集成的ZnO/CuO界面上形成Zn-O-Cu键,从而实现原子级异质界面。由于前驱体的独特结构,Ov-ZnO/CuO形成由超小纳米晶体组成的分层多孔微球。此外,通过改变前驱体的Cu:Zn摩尔比,可以调节Ov- zno /CuO的Ov含量。s方案电荷转移机制表明,在Ov- zno /CuO-10%中,原子级异质界面、合适的Ov含量、cuo衍生光热效应和短电荷扩散距离的协同作用有效地促进了电荷的分离和转移,最终在4个循环后获得了9.13 μmol g-1 h-1的CO产率和93.7%的保留率。该研究为提高光催化CO2还原活性提供了有效途径,并为基于组分结构特征有针对性地设计异质结提供了新的思路。
Damage evolution of CFRP laminates subjected to cryogenic flexure loading using in situ X-ray computed tomography
Panding Wang, Yingxue Bai, Zeang Zhao, Shengyu Duan, Yuanchen Li, Hongshuai Lei
doi:10.1016/j.composites b .2025.113171
低温弯曲载荷下CFRP层合板损伤演化的原位x射线计算机断层扫描
Studying the damage evolution and leakage behavior of carbon fiber-reinforced polymer (CFRP) composites subjected to complex loading in cryogenic propellant tanks has been challenging for the research community. The development of a novel in situ cryogenic flexure test for monitoring the damage evolution of plain woven CFRP composites using X-ray computed tomography (CT) is presented in this study. In situ flexure testing was conducted at temperatures of room temperature (RT), -100 °C and -180 °C. The defects were extracted and quantified from in situ CT images. The effects of the stress state and temperature on cryogenic damage evolution behavior are discussed. CT, optical microscopy and scanning electron microscopy characterization revealed the damage evolution and failure mechanis ms of CFRP composites under flexural loading. Intralaminar cracks and interlaminar delamination were induced under cryogenic mechanical loading, and leakage paths formed. The leakage properties of the CFRP composites under various pressures at RT, -100°C and -180 °C were measured by permeability testing.
研究碳纤维增强聚合物(CFRP)复合材料在低温推进剂储罐中复杂载荷作用下的损伤演化和泄漏行为一直是研究界面临的挑战。本研究提出了一种新型的原位低温弯曲试验,用于使用x射线计算机断层扫描(CT)监测平纹编织CFRP复合材料的损伤演变。在室温(RT)、-100°C和-180°C的温度下进行原位弯曲测试。从原位CT图像中提取和量化缺陷。讨论了应力状态和温度对低温损伤演化行为的影响。CT、光学显微镜和扫描电镜表征揭示了CFRP复合材料在弯曲载荷作用下的损伤演化和破坏机制。低温机械载荷作用下,引起层内裂纹和层间剥离,形成泄漏通道。通过渗透性测试测试了CFRP复合材料在RT、-100℃和-180℃不同压力下的泄漏性能。
Multi-scale mechanis m insight of elastomer toughened thermoplastic composites
Zheng Li, Kaiyin Xiao, Tong Li, Bo Wang, Peng Hao, Zebei Mao, Kaifan Du
doi:10.1016/j.compscitech.2025.111434
弹性体增韧热塑性复合材料的多尺度机理研究
This study elucidates a multi-applicability mechanis m of elastomer-toughened brittle thermoplastics polymers through experimental methods and multiscale an alysis. Polyolefin elastomer (POE) and glycidyl methacrylate-modified POE (POE-GMA) were used to toughen thermoplastic polymers polyphenylene sulfide (PPS) and polybutylene terephthalate (PBT). It was found that s mall amounts of POE-GMA could enhance the fracture energy of PBT and PPS by 167% and 415%, while only sacrificing 5.3%∼11.6% of strength or rigidity, and the lower the inherent toughness of the polymer, the better the toughening effect, whereas POE showed no significant effect. Molecular dynamics simulations indicate that the GMA groups enhance interactions between POE-GMA and polymers, promoting POE-GMA diffusion into the polymer matrix and improving dispersion. Further finite element modeling indicates that s maller and more dispersed elastomer particles can induce more microcracks, enhancing energy absorption and consequently increasing the fracture energy, thereby improving toughness. This multi-applicability mechanis m provides crucial insights for designing polymer composites that balance toughness and rigidity.
本研究通过实验方法和多尺度分析,阐明了弹性体增韧脆性热塑性聚合物的多适用机理。采用聚烯烃弹性体(POE)和甲基丙烯酸缩水甘油酯改性POE (POE- gma)对热塑性聚合物聚苯硫醚(PPS)和聚对苯二甲酸丁二酯(PBT)进行增韧。结果发现,少量POE- gma可使PBT和PPS的断裂能分别提高167%和415%,而强度或刚度仅损失5.3% ~ 11.6%,聚合物的固有韧性越低,增韧效果越好,POE无显著作用。分子动力学模拟表明,GMA基团增强了POE-GMA与聚合物之间的相互作用,促进了POE-GMA向聚合物基体的扩散,改善了聚合物的分散性。进一步的有限元模拟表明,弹性体颗粒越小、越分散,产生的微裂纹越多,增强了能量吸收,从而提高了断裂能,从而提高了韧性。这种多用途机制为设计平衡韧性和刚性的聚合物复合材料提供了重要的见解。